She's one of the most beautiful, talented, intelligent actresses in the world - but Angelina still gets jealous when it comes to her men performing sex scenes in film.
Ex husband Billy Bob Thornton told The Sun that he came into difficulty when having to explain over the phone that he had to film sex scenes with actresses such as Halle Berry.
He recalled the moment when Angelina, 38, did not sound too happy when he told her about the explicit sex scene in Monster's Ball, which he filmed in 2001.
Older and wiser: Billy Bob Thornton poses with his longterm partner, Connie Angland
Thornton told : 'She is one of the most beautiful women in the world and I am talking on the phone to my wife, (Angelina) and she says: "What have you been doing today?"
'And I say: "Oh, I did that sex scene with Halle Berry." You are then asked if you actually touched her. I say: "I had to - it's in the scene."
'I blew my marriage to Angelina. I thought I was not good enough for her and I was too insecure. We are still friends.'
Like a couple in love: Billy Bob Thorton and Angelina looked like a couple in love as they posed together at a premiere in 2001
Angelina is thought to be the reason behind Brad's decision to avoid accepting scripts which involve sex scenes.
Since the couple met in 2005, Brad now keeps as far away from them as possible.
Earlier this year, Brad's friend Frank Pollaro revealed: 'This is a guy who has tried not to do any sexy scenes with other women since he’s met Angelina. He’s crazy about her, and she’s the same way about him.'
Jolie and Thorton, who were married for three years between 2000 and 2003, famously wore vials of each other's blood around their necks.
Intimate: Halle Berry and Billy Bob Thornton film an intimate scene from the film Monster's Ball
Recently the actor, who has been married five times in total, was seen in New York hand-in-hand with a mystery woman who at first sight could have been mistaken for his long term girlfriend, Connie.
The 58-year-old actor enjoyed a sunshine stroll with the unnamed brunette in the Chelsea district of New York.
Their amorous appearance suggests that Billy Bob and Connie, a make-up effects crew member, may have terminated their relationship.